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Код

var customBinding = new CustomBinding();
            var sec = (AsymmetricSecurityBindingElement)SecurityBindingElement.CreateMutualCertificateBindingElement(MessageSecurityVersion.WSSecurity10WSTrustFebruary2005WSSecureConversationFebruary2005WSSecurityPolicy11BasicSecurityProfile10);
            var userNameToken = new UserNameSecurityTokenParameters();
            sec.EnableUnsecuredResponse = true;
            sec.EndpointSupportingTokenParameters.Signed.Add(userNameToken);
            sec.MessageSecurityVersion = MessageSecurityVersion.WSSecurity10WSTrustFebruary2005WSSecureConversationFebruary2005WSSecurityPolicy11BasicSecurityProfile10;
            sec.IncludeTimestamp = true;
            sec.SecurityHeaderLayout = SecurityHeaderLayout.Strict;
            sec.AllowInsecureTransport = true;
            customBinding.Elements.Add(sec);
            customBinding.Elements.Add(new TextMessageEncodingBindingElement(MessageVersion.Soap11, Encoding.UTF8));
            customBinding.Elements.Add(new HttpsTransportBindingElement());

            string url = "<url>";
            Uri uri = new Uri(url);
            DnsEndpointIdentity identity = new DnsEndpointIdentity("<username>");
            EndpointAddress address = new EndpointAddress(uri, identity, new AddressHeaderCollection());

            string certPath1 = "D:\\2\\<cert1>.p12";
            var cert1 = new X509Certificate2(certPath1);
            string certPath2 = "D:\\2\\<cert2>.p12";
            var cert2 = new X509Certificate2(certPath2, "<password>");
            paymentService.PaymentServiceClient client = new paymentService.PaymentServiceClient(customBinding, address);
            client.ClientCredentials.UserName.UserName = "<user>";
            client.ClientCredentials.UserName.Password = "<password>";
            client.ClientCredentials.ServiceCertificate.DefaultCertificate = cert1;
            client.ClientCredentials.ClientCertificate.Certificate = cert2;
            try
            {
                client.Open();
                string s = client...;
                MessageBox.Show(s);
                client.Close();
            }
            catch (Exception ex)
            {
                textBox1.Text = ex.ToString();
                client.Close();
            }